19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

N. M. Cantillo; L. Li; J. Peng; G. A. Goenaga; T. A. Zawodzinski

doi:10.1149/08008.0259ecst

¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

N. M. Cantillo, L. Li, J. Peng, G. A. Goenaga, T. A. Zawodzinski

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using ¹⁹F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

Original language	English
Title of host publication	ECS Transactions
Editors	D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, H. Xu
Publisher	Electrochemical Society Inc.
Pages	259-268
Number of pages	10
Edition	8
ISBN (Electronic)	9781607688259
ISBN (Print)	9781623324773
DOIs	https://doi.org/10.1149/08008.0259ecst
Publication status	Published - 2017
Externally published	Yes
Event	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting - National Harbor, United States Duration: Oct 1 2017 → Oct 5 2017

Publication series

Name	ECS Transactions
Number	8
Volume	80
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting
Country/Territory	United States
City	National Harbor
Period	1/10/17 → 5/10/17

Bibliographical note

Publisher Copyright:
© The Electrochemical Society.

ASJC Scopus Subject Areas

General Engineering

Access to Document

10.1149/08008.0259ecst

Cite this

Cantillo, N. M., Li, L., Peng, J., Goenaga, G. A., & Zawodzinski, T. A. (2017). ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. In D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, ... H. Xu (Eds.), ECS Transactions (8 ed., pp. 259-268). (ECS Transactions; Vol. 80, No. 8). Electrochemical Society Inc.. https://doi.org/10.1149/08008.0259ecst

¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. / Cantillo, N. M.; Li, L.; Peng, J. et al.
ECS Transactions. ed. / D. J. Jones; F. Buechi; K. E. Swider-Lyons; P. N. Pintauro; H. Uchida; T. J. Schmidt; B. S. Pivovar; H. A. Gasteiger; A. Z. Weber; P. A. Shirvanian; J. M. Fenton; T. F. Fuller; K. Shinohara; K. A. Perry; P. Strasser; C. Coutanceau; S. Mitsushima; R. A. Mantz; S. Narayan; V. Ramani; K. E. Ayers; Y.-T. Kim; H. Xu. 8. ed. Electrochemical Society Inc., 2017. p. 259-268 (ECS Transactions; Vol. 80, No. 8).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Cantillo, NM, Li, L, Peng, J, Goenaga, GA & Zawodzinski, TA 2017, ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. in DJ Jones, F Buechi, KE Swider-Lyons, PN Pintauro, H Uchida, TJ Schmidt, BS Pivovar, HA Gasteiger, AZ Weber, PA Shirvanian, JM Fenton, TF Fuller, K Shinohara, KA Perry, P Strasser, C Coutanceau, S Mitsushima, RA Mantz, S Narayan, V Ramani, KE Ayers, Y-T Kim & H Xu (eds), ECS Transactions. 8 edn, ECS Transactions, no. 8, vol. 80, Electrochemical Society Inc., pp. 259-268, Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting, National Harbor, United States, 1/10/17. https://doi.org/10.1149/08008.0259ecst

Cantillo NM, Li L, Peng J, Goenaga GA, Zawodzinski TA. ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. In Jones DJ, Buechi F, Swider-Lyons KE, Pintauro PN, Uchida H, Schmidt TJ, Pivovar BS, Gasteiger HA, Weber AZ, Shirvanian PA, Fenton JM, Fuller TF, Shinohara K, Perry KA, Strasser P, Coutanceau C, Mitsushima S, Mantz RA, Narayan S, Ramani V, Ayers KE, Kim YT, Xu H, editors, ECS Transactions. 8 ed. Electrochemical Society Inc. 2017. p. 259-268. (ECS Transactions; 8). doi: 10.1149/08008.0259ecst

Cantillo, N. M. ; Li, L. ; Peng, J. et al. / ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. ECS Transactions. editor / D. J. Jones ; F. Buechi ; K. E. Swider-Lyons ; P. N. Pintauro ; H. Uchida ; T. J. Schmidt ; B. S. Pivovar ; H. A. Gasteiger ; A. Z. Weber ; P. A. Shirvanian ; J. M. Fenton ; T. F. Fuller ; K. Shinohara ; K. A. Perry ; P. Strasser ; C. Coutanceau ; S. Mitsushima ; R. A. Mantz ; S. Narayan ; V. Ramani ; K. E. Ayers ; Y.-T. Kim ; H. Xu. 8. ed. Electrochemical Society Inc., 2017. pp. 259-268 (ECS Transactions; 8).

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